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Palladium-catalyzed domino spirocyclization of [60]fullerene: synthesis of diverse [60]fullerene-fused spiro[4,5]/[5,5] derivatives.
- Source :
-
Chemical Communications . 1/4/2021, Vol. 57 Issue 1, p49-52. 4p. - Publication Year :
- 2021
-
Abstract
- Herein a new, general and practical method for the spirocyclization of [60]fullerene through a palladium-catalyzed domino Heck/C–H activation reaction is presented. A wide range of novel [60]fullerene-fused spirocyclic derivatives can be easily and flexibly synthesized with a broad substrate scope and excellent functional-group tolerance. A plausible mechanism involving an alkyl Pd(II) species as a key intermediate has been proposed. [ABSTRACT FROM AUTHOR]
- Subjects :
- *FULLERENES
*SPECIES
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 57
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 147965519
- Full Text :
- https://doi.org/10.1039/d0cc07143a