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Fluorescence quenching mechanism of 9-hydroxyphenal-1-one carbon quantum dots by Cu2+ ions: An experimental and computational investigation.
- Source :
-
Journal of Photochemistry & Photobiology A: Chemistry . Mar2021, Vol. 408, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
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Abstract
- The fluorescence quenching mechanism of the HPHN-CQDs in the presence of Cu2+ ions. • HPHN-CQDs are prepared using pure HPHN with known molecular and crystal structures. • HPHN-CQDs exhibit an excellent luminescent recognition toward Cu2+ ions with a detection limit of 4.8 nM. • The orbital interaction diagram indicated that the presence of Cu2+ can affect the luminescence behavior of HPHN. • The electron is transferred from the excited HPHN to the 3d orbital of Cu2+. • The fluorescence rate constant of HPHN-Cu2+ was substantially decreased compared with that of HPHN. A combination of experimental and computational methods was used to study the Cu2+ ions recognition by 9-hydroxyphenal-1-one carbon quantum dots (HPHN-CQDs). HPHN-CQDs were proved to be an efficient fluorescent probe that can detect Cu2+ ions with high selectivity and sensitivity, and the detection limit was 4.8 nM. We performed a detailed analysis of the fluorescence quenching mechanism of HPHN-CQDs by means of density functional theory (DFT) and time-dependent density functional theory (TDDFT). The orbital interaction diagram indicated that the presence of Cu2+ can affect the luminescence behavior of HPHN by changing its orbital distribution. In addition, the electron was transferred from the excited HPHN to the 3d orbital of Cu2+, which would hinder the recombination of electron-hole pairs and promote the fluorescence quenching of HPHN-CQDs. The photophysical process revealed that the fluorescence rate constant of HPHN-Cu2+ was substantially decreased compared with that of HPHN, which is consistent with the experimental results. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10106030
- Volume :
- 408
- Database :
- Academic Search Index
- Journal :
- Journal of Photochemistry & Photobiology A: Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 148234005
- Full Text :
- https://doi.org/10.1016/j.jphotochem.2020.113103