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Na3V2(PO4)3/C composites as low‐cost and high‐performance cathode materials for sodium‐ion batteries.
- Source :
-
International Journal of Energy Research . 3/10/2021, Vol. 45 Issue 3, p4534-4542. 9p. - Publication Year :
- 2021
-
Abstract
- Summary: The carbon layer acting as a conductive medium is beneficial to overcoming the comparatively inferior electronic conductivity of Na3V2(PO4)3. Based on this, Na3V2(PO4)3/C composites with diverse ratios of citric acid are synthetized via rheological phase reaction way in this work. The consequences display that the Na3V2(PO4)3/C‐1.5 composite brings a higher initial discharge capacity of 113.2 mAh g−1 at a current rate of 1 C with coulombic efficiency above 99% during all cycles. The discharge capacity retains at 117.6 mAh g−1 at the 100th cycle. Even at the high current densities of 5 C and 10 C, the composite also shows superior cycling performance with negligible capacity fading. Its discharge capacities decline from 97 to 92.6 mAh g−1 at 5 C and from 85.3 to 83.7 mAh g−1 at 10 C. These remarkable outcomes arise from its preferable morphology with suitable carbon coating because both excess and skimpy carbon seriously affect the microstructure and electrochemical properties of Na3V2(PO4)3/C composites. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CITRIC acid
*STORAGE batteries
*DENSITY currents
*CATHODES
*MATERIALS
Subjects
Details
- Language :
- English
- ISSN :
- 0363907X
- Volume :
- 45
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- International Journal of Energy Research
- Publication Type :
- Academic Journal
- Accession number :
- 148430166
- Full Text :
- https://doi.org/10.1002/er.6122