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Temporary (P=O) directing group enabled carbazole ortho arylation via palladium catalysis.

Authors :
Qi, Zhi-Chao
Lou, Qin-Xin
Niu, Yuan
Yang, Shang-Dong
Source :
Chemical Communications. 2/25/2021, Vol. 57 Issue 16, p2021-2024. 4p.
Publication Year :
2021

Abstract

A palladium-catalyzed, temporary P(O) directing group assisted C–H bond arylation of carbazoles was achieved. The release of the directing group occurs spontaneously in the reaction and the mechanistic studies indicate that acid is essential for N–P bond cleavage. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
57
Issue :
16
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
148905803
Full Text :
https://doi.org/10.1039/d0cc07596e