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Nonlinear Optical Oxythiophosphate Approaching the Good Balance with Wide Ultraviolet Transparency, Strong Second Harmonic Effect, and Large Birefringence.
- Source :
-
Angewandte Chemie . Mar2021, Vol. 133 Issue 12, p6456-6460. 5p. - Publication Year :
- 2021
-
Abstract
- Ultraviolet (UV) transparency, second harmonic effect and optical birefringence are three vital but mutually restrictive factors in the application of UV nonlinear optical (NLO) materials. It is difficult for traditional phosphates to achieve a good balance among these factors. In this communication, we propose that the structural evolution of the NLO motif from traditional phosphate to oxythiophosphate would enhance the birefringence and second harmonic generation (SHG) effect while maintaining wide UV transparency, which is confirmed by first‐principles calculations and preliminary experimental measurements. Following this strategy, we predict that, compared with the well‐known NLO phosphate KH2PO4, the oxythiophosphate KH2PO3S exhibits better balance for the UV NLO performance, including wide UV transparency (UV cutoff down to 203 nm), strong SHG effect (ca. 0.9 pm V−1), and large birefringence (ca. 0.1 at 1 μm) with short phase‐matching SHG output wavelength (≈214 nm). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 133
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 149132634
- Full Text :
- https://doi.org/10.1002/ange.202016013