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Synthesis of Isatin‐Hydrazones from 3‐Diazo Oxindoles and Sulfoxonium Ylides under Catalyst‐ and Additive‐Free Conditions.

Authors :
Tian, Yu
Zhang, Zunting
Wang, Tao
Source :
European Journal of Organic Chemistry. 3/12/2021, Vol. 2021 Issue 10, p1592-1595. 4p.
Publication Year :
2021

Abstract

A facile synthesis of isatin‐hydrazones from 3‐diazo oxindoles and sulfoxonium ylides under catalyst‐ and additive‐free conditions is described. A plausible reaction pathway is proposed for the transformation, in which diazo compounds play as electrophiles to react with nucleophilic sulfoxonium ylides. The reaction mechanism is supported by the experimental evidence. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
1434193X
Volume :
2021
Issue :
10
Database :
Academic Search Index
Journal :
European Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
149246405
Full Text :
https://doi.org/10.1002/ejoc.202100060