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Ultrathin Monolayer Mn2+‐Alloyed 2D Perovskite Colloidal Quantum Wells.
- Source :
-
Advanced Optical Materials . 3/18/2021, Vol. 9 Issue 6, p1-7. 7p. - Publication Year :
- 2021
-
Abstract
- Atomically thin monolayer Mn2+‐alloyed 2D Ruddlesden–Popper (RP) perovskite colloidal quantum wells (CQWs) are demonstrated as efficiently tunable emitter with wide color gamut. Ultrathin character evidenced by the well‐controlled thickness of ≈1.8 nm, leads to alloying rather than doping mechanism reported previously, which facilitates uniform and large‐ratio substitution of Pb2+ by Mn2+ within the metal‐halide octahedra layer. Photoluminescence spectra reveal dual color emissions constituted by blue‐greenish intrinsic excitonic emission and reddish Mn2+ emission with a high photoluminescence quantum yield (PLQY) up to 32%. Two individual channels are created for precisely targeting the emission color in a wide gamut by finely controlling the excitonic emission via the chemical compositions of Br/I and the Mn2+ emission via the chemical compositions of Mn/Pb, respectively. Experimentally, high quality single‐component white emitter ultrathin CQWs are achieved with CIE coordinate value of (0.33, 0.32), 21% PLQY, and good film processibility. The results reveal great potential as applicant for next generation lighting and display technologies. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 21951071
- Volume :
- 9
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Advanced Optical Materials
- Publication Type :
- Academic Journal
- Accession number :
- 149376603
- Full Text :
- https://doi.org/10.1002/adom.202001135