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Postsynthetic polymer-ligand exchange hybridization in M-MOF-74 composites.
- Source :
-
Journal of Coordination Chemistry . Jan-Feb2021, Vol. 74 Issue 1-3, p178-189. 12p. - Publication Year :
- 2021
-
Abstract
- A series of new polymer-inorganic composites has been synthesized from poly(amic acid) (PAA) and various M-MOF-74 (M = Mg, Mn, Co, Ni, Zn) frameworks using a postsynthetic ligand exchange strategy, wherein ligand moieties built into the PAA backbone are exchanged with MOF-bound ligands. The reaction is monitored by UV-vis spectroscopy in order to compare exchange rates for different metal ions, and the resulting composites are characterized by powder X-ray diffraction and scanning electron microscopy. This method of polymer-ligand exchange (PLE) hybridization has only been previously demonstrated using Zn2+-carboxylate and Zn2+-imidazolate frameworks; therefore, this work further reveals the versatility of PLE by showing that exchange is possible for several additional metal ions, as well as frameworks containing 2,5-dihydroxyterephthalate ligands. [ABSTRACT FROM AUTHOR]
- Subjects :
- *X-ray powder diffraction
*AMIC acids
*SCANNING electron microscopy
*METAL ions
Subjects
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 74
- Issue :
- 1-3
- Database :
- Academic Search Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 149554355
- Full Text :
- https://doi.org/10.1080/00958972.2021.1876852