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Inhibition mechanism of capacity degradation in Mg-substituted LaY2-xMgxNi9 hydrogen storage alloys.
- Source :
-
Journal of Alloys & Compounds . Aug2021, Vol. 873, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
-
Abstract
- • Mg substitution destabilizes LaY 2 Ni 9 phase and reduces maximum discharge capacity. • Inhibition of amorphization is confirmed by TEM and amorphization formation criterion. • Inhibition of the pulverization and amorphization enhances capacity retention. • LaY 1.25 Mg 0.75 Ni 9 alloy exhibits good overall electrochemical properties. [Display omitted] To elucidate the effect of Mg substitution on the electrochemical properties of LaY 2 Ni 9 alloys and its thermodynamic mechanisms, the cyclic stability, maximum discharge capacity (MDC), microstructure evolution, hydrogen induced amorphization (HIA), pulverization, formation energy, and amorphization formation criteria of LaY 2- x Mg x Ni 9 (x = 0, 0.25, 0.50, 0.75, and 1.00) alloys are investigated. The calculated formation energy indicates that Mg substitution destabilizes LaY 2 Ni 9 phases and is responsible for decrement of phase fraction of LaY 2 Ni 9 phases. The consumption of LaY 2 Ni 9 phase and the generation of (La, Y) 2 Ni 7 phase improve the cyclic stability by inhibiting the pulverization but reduce the MDC of the alloys. The amorphization formation criterion demonstrates that Mg substitution inhibits the HIA as verified by transmission electron microscopy results, which benefits both the MDC and cyclic stability of the alloys. The LaY 1.25 Mg 0.75 Ni 9 alloy exhibits good overall electrochemical properties with the MDC of 308.4 mAh/g and capacity retention after 100 cycles of 69.0%. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 873
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 150227812
- Full Text :
- https://doi.org/10.1016/j.jallcom.2021.159826