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Reactions of Alkyl 2-(Bromozinc)acylates with N-Chloro- and N-Bromodiethylamines.
- Source :
-
Russian Journal of General Chemistry . Apr2021, Vol. 91 Issue 4, p602-605. 4p. - Publication Year :
- 2021
-
Abstract
- The reaction of alkyl 2-(bromozinc)acylates, obtained from ethyl bromoacetate (or butyl 2-bromobutanoate, or butyl 2-bromo-2-methylpropanoate) under the action of zinc, with N-chloro- or N-bromodiethylamine in tetrahydrofuran at 20–25°C under argon for 2 h resulted in the formation of diethyl succinate (or dibutyl 2,3-diethyl succinate, or dibutyl tetramethyl succinate) and diethylamine instead of the expected products of the nucleophilic substitution of the halogen with the 2-alkoxycarbonylalkyl residue. An anion-radical reaction mechanism was proposed. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10703632
- Volume :
- 91
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Russian Journal of General Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 150429811
- Full Text :
- https://doi.org/10.1134/S1070363221040046