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Investigation on the structural quality dependent electromagnetic interference shielding performance of few-layer and lamellar Nb2CTx MXene nanostructures.
- Source :
-
Journal of Alloys & Compounds . Oct2021, Vol. 877, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
-
Abstract
- Tunable Electromagnetic Interference (EMI) shielding behaviors of 2D MXene (Nb 2 CT x) were explored via different exfoliation conditions. Stacked, lamellar few-layer, oxygen-related surface functional groups, and structural defects along with oxidative products of Nb 2 CT x were identified by tuning chemical etching conditions during one-step exfoliation process. Exfoliation of Nb 2 CT x with a tightly packed stacked structure remarked at lower etching times. The unpacking of Nb 2 CT x into lamellar morphology followed by separated few-layer Nb 2 CT x remarked at moderate etching time, whereas structural misalignment, defects, and oxidation of Nb 2 CT x occurred during prolonged chemical etching times. Synergistic effect of one-step extracted few-layers and lamellar structured Nb 2 CT x favorably enrich the assembly of multiple electrical conductive pathways responsible for absorption dominated EMI shielding performance in X- and Ku-band region. The assembled wax nanocomposites with 80% of Nb 2 CT x loading exfoliated at 100 h etching time at a thickness of 1 mm exhibited EMI shielding effectiveness of about 44.09 ± 1.99 dB at 12 GHz, and its EMI attenuation mechanism explained by conduction and eddy current loss. The combined action of few-layer and lamellar Nb 2 CT x nanostructures could be interesting for making novel shielding materials; open a new avenue for niobium series in the MXene family for elaborated applications. • Investigation on one step exfoliation of few-layer transition metal carbide (Nb2CTx) MXene by tuning exfoliation conditions. • The Nb 2 CT x wax nanocomposites exhibited EMI shielding effectiveness of about 44.09±1.99 dB at 12 GHz. • Synergistic action of few-layer and laminar Nb 2 CT x favorable conducting network lead higher absorbing capacity of EM waves. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 877
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 150588803
- Full Text :
- https://doi.org/10.1016/j.jallcom.2021.160235