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Tetraphenylethylene based amphiphilic derivatives: The self-assembly, photo-responsiveness and their application for erasable fluorescent ink.
- Source :
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Dyes & Pigments . Sep2021, Vol. 193, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
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Abstract
- Since the discovery of aggregation induced emission (AIE) phenomenon, various stimuli-responsive materials have been rapidly developed. However, the development of self-assembled amphiphilic light-responsive materials in aqueous solution needs to be solved urgently. In this work, three new amphiphilic tetraphenylethylene (TPE) derivatives (TPE-1 , TPE-2 and TPE-3) with AIE properties and photochromism were synthesized and investigated. Owing to the different electron-donating abilities of the three groups attached to TPE units, the TPE-1 , TPE-2 and TPE-3 displayed blue-green, yellow-green, and orange fluorescence emission in the aggregation state respectively. Furthermore, ordered nanoparticles formed via self-assembly in aqueous solution showed interesting photocyclization behaviors, which lead to fluorescence quenching under ultraviolet light irradiation (λ = 365 nm). Therefore, the compounds can be used as anti-counterfeiting ink in the information encryption due to their amphiphilicity and photo-responsiveness. This work contributes new members to the amphiphilic light-responsive materials family and demonstrates the potential for applications in the fields of optical information storage, information security protection, and erase/rewrite systems. [Display omitted] • Three tetraphenylethylene derivatives with AIE properties and photochromism were synthesized and investigated. • The designed compounds displayed different fluorescence emission in the aggregation state. • The ordered nanoparticles formed via self-assembly in aqueous solution showed interesting photocyclization behaviors. • The compounds were successfully used as anti-counterfeiting ink in the information encryption. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01437208
- Volume :
- 193
- Database :
- Academic Search Index
- Journal :
- Dyes & Pigments
- Publication Type :
- Academic Journal
- Accession number :
- 151123698
- Full Text :
- https://doi.org/10.1016/j.dyepig.2021.109479