Cation-translocation based isomerism offers a tool for the expansion of compressed helicates.

Authors :: Mevissen, Christian
Sommer, David
Vasanthakumar, Sabarina
Truong, Khai-Nghi
Rissanen, Kari
Albrecht, Markus
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry. 7/21/2021, Vol. 50 Issue 27, p9372-9375. 4p.
Publication Year :: 2021
Abstract: A series of compressed M[Li313Ti2] (M = Li, Na, K, Rb, Cs) and expanded helicates M4[13Ti2] has been obtained. The helicates Li3[M13Ti2] or M4[13Ti2] with M = Na+, K+, Rb+, or Cs+ adopt the expanded structure in solution. By crystallization the compressed structures M[Li313Ti2] (M = Na, Rb) are obtained. This represents an example of cation-translocation based isomerism. [ABSTRACT FROM AUTHOR]

Language :: English
ISSN :: 14779226
Volume :: 50
Issue :: 27
Database :: Academic Search Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 151363538
Full Text :: https://doi.org/10.1039/d1dt01707a

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