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Cation-translocation based isomerism offers a tool for the expansion of compressed helicates.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 7/21/2021, Vol. 50 Issue 27, p9372-9375. 4p. - Publication Year :
- 2021
-
Abstract
- A series of compressed M[Li313Ti2] (M = Li, Na, K, Rb, Cs) and expanded helicates M4[13Ti2] has been obtained. The helicates Li3[M13Ti2] or M4[13Ti2] with M = Na+, K+, Rb+, or Cs+ adopt the expanded structure in solution. By crystallization the compressed structures M[Li313Ti2] (M = Na, Rb) are obtained. This represents an example of cation-translocation based isomerism. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ISOMERISM
*ALKALI metals
*CRYSTALLIZATION
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 50
- Issue :
- 27
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 151363538
- Full Text :
- https://doi.org/10.1039/d1dt01707a