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A Green Approach for Electrochemical Thiocyanation of Nitrogen Heterocycles with KSCN at Platinum Electrode.
- Source :
-
Russian Journal of Electrochemistry . Jun2021, Vol. 57 Issue 6, p625-635. 11p. - Publication Year :
- 2021
-
Abstract
- A novel, convenient and economical method was developed for the anodic thiocyanation of nitrogen-containing aromatic and heteroaromatic compounds by constant potential electrolysis of potassium thiocyanate in an undivided cell under mild condition (25°C, Pt anode, CH3CN) with yields up to 91%. The products were characterized by spectroscopic methods and a mechanism was deduced from voltammetry studies. The salient features of proposed procedure ensures mild reaction conditions, shortest reaction time, accelerated rate, high yield, cost-effectiveness, selectivity, and simple work up procedure, Which provide additional advantages in the context of green chemistry. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10231935
- Volume :
- 57
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Russian Journal of Electrochemistry
- Publication Type :
- Academic Journal
- Accession number :
- 151385642
- Full Text :
- https://doi.org/10.1134/S1023193520120137