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The effect of Ni oxidation state on the crystal structure and electrochemical properties of LiNi0.8Co0.1Mn0.1O2 cathode material for highly reversible lithium storage.
- Source :
-
Journal of Alloys & Compounds . Nov2021, Vol. 882, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
-
Abstract
- • Micron single crystals of LiNi 0.8 Co 0.1 Mn 0.1 O 2 were prepared by molten salt method. • SC-NCM has lower cationic mixing accompanying with ordered growth of micron crystal. • Ni(III) in SC-NCM is majority benefiting for cyclic stability. • After 300 cycles at 5C rate SC-NCM remains 80.7 mAh g−1 and retention 62.0%. • Micron single crystals on electrochemical property benefit for structure stability. In this work, Ni-rich layered micron-sized LiNi 0.8 Co 0.1 Mn 0.1 O 2 (SC-NCM) single crystals were prepared by wet ball-milling and molten-salt methods. Through X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectrometry (XPS), the differences between SC-NCM and a commercial polycrystalline micron-sized NCM material (M-NCM) were compared. An extended sintering process for SC-NCM plays a role in decreasing cationic mixing accompanied by the ordered growth of single crystals. The SC-NCM sample presents homogeneous micron-sized crystals. The Ni3+ content in SC-NCM constitutes 90.45% of the total Ni content, while the Ni3+ in M-NCM constitutes only 68.49%. The existence of Ni2+ in ternary cathode materials is harmful to electrochemical stability and cyclic stability. The initial specific discharge capacity of SC-NCM (168 mAh g−1) is lower than that of M-NCM (187 mAh g−1); however, M-NCM shows a rapid decline in capacities and voltage plateaus from the 1st to 180th cycle. After 300 cycles at a 5 C rate, M-NCM remains only 42 mAh g−1 with a capacity retention rate of only 25.6% in comparison with SC-NCM with a remaining capacity of 80.7 mAh g−1 and a capacity retention of 62.0%. The effect of micron-sized single crystals on electrochemical properties during redox reactions is negative in terms of conductivity but positive in terms of structural stability. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 882
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 151556662
- Full Text :
- https://doi.org/10.1016/j.jallcom.2021.160642