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Photoinduced transition-metal and external photosensitizer free cross-coupling of aryl triflates with trialkyl phosphites.
- Source :
-
Chemical Communications . 9/4/2021, Vol. 57 Issue 68, p8429-8432. 4p. - Publication Year :
- 2021
-
Abstract
- Photoinduced phosphonation of aryl triflates with trialkyl phosphites via a tandemsingle-electron-transfer, C-O bond cleavage and Arbuzov rearrangement process in the absence of transition-metal and external photosensitizer is reported herein. The protocol features good functional group compatibility and mild reaction conditions, providing various aryl phosphates in good to high yields. Furthermore, this strategy allows the late-stage phosphonation of complex and biologically active compounds. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 57
- Issue :
- 68
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 152113859
- Full Text :
- https://doi.org/10.1039/d1cc03496k