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Electrochemical reduction of fluoroalkyl sulfones for radical fluoroalkylation of alkenes.
- Source :
-
Chemical Communications . 9/11/2021, Vol. 57 Issue 70, p8750-8753. 4p. - Publication Year :
- 2021
-
Abstract
- Radical fluoroalkylation of alkenes has been developed by electrochemical reduction of fluoroalkyl sulfones. A series of electron-deficient alkenes readily undergo hydrofluoroalkylation in good to excellent yields. This chemistry represents the first example of electrochemical generation of fluoroalkyl radicals from sulfones, which are used for practical radical fluoroalkylation of organic compounds. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SULFONES
*ALKENES
*ORGANIC compounds
*ELECTROLYTIC reduction
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 57
- Issue :
- 70
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 152224191
- Full Text :
- https://doi.org/10.1039/d1cc03258e