Impact of superheated steam on the moisture transfer, structural characteristics and rheological properties of wheat starch.

Superheated steam treatment (SST) can improve cereal-based foodstuff quality. Starch is the major component of cereal-based foodstuffs, playing a key role in food quality. For understanding the effect of SST on the moisture distribution, lamellar structure and molecular weight of wheat starch, the low-field nuclear magnetic resonance (LF-NMR), small angle X-ray scattering (SAXS) and size exclusion chromatography were employed. Compared with native starch, SST reduced the average thickness of crystalline layer and induced the depolymerization of starch molecules, which were attributed to the limited moisture transfer resulting in the partial gelatinization of starch granules. The structural variations had a synergistic effect on the rheological properties of starch samples. Upon SST, treated samples exhibited a weaker pseudoplasticity behavior and increased the deformability and mobility of gels systems. Furthermore, the lower tanδ values of treated starch samples were observed, indicating that the gels systems tended to the solid-like behaviors. [Display omitted] • Superheated steam treatment (SST) changed the water distribution of wheat starch. • SST transmuted the crystalline lamellae into the amorphous lamellae of wheat starch. • SST depolymerized starch molecular structure and decreased its molecular weight. • SST weakened the gels systems but increased its deformability and mobility. [ABSTRACT FROM AUTHOR]