Back to Search
Start Over
Radical Stabilization of a Tripyridinium–Triazine Molecule Enables Reversible Storage of Multiple Electrons.
- Source :
-
Angewandte Chemie . 9/13/2021, Vol. 133 Issue 38, p21089-21093. 5p. - Publication Year :
- 2021
-
Abstract
- A novel organic molecule, 2,4,6‐tris[1‐(trimethylamonium)propyl‐4‐pyridiniumyl]‐1,3,5‐triazine hexachloride, was developed as a reversible six‐electron storage electrolyte for use in an aqueous redox flow battery (ARFB). Physicochemical characterization reveals that the molecule evolves from a radical to a biradical and finally to a quinoid structure upon accepting four electrons. Both the diffusion coefficient and the rate constant were sufficiently high to run a flow battery with low concentration and kinetics polarization losses. In a demonstration unit, the assembled flow battery affords a high specific capacity of 33.0 Ah L−1 and a peak power density of 273 mW cm−2. This work highlights the rational design of electroactive organics that can manipulate multi‐electron transfer in a reversible way, which will pave the way to development of energy‐dense, manageable and low‐cost ARFBs. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 133
- Issue :
- 38
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 152292102
- Full Text :
- https://doi.org/10.1002/ange.202107216