Microfluidic non-enzymatic biofuel cell integrated with electrodeposited metallic catalysts on a paper based platform.

Sustainable power generation for portable electronic devices is of high interest due to increasing energy demands. Miniaturized biofuel cells are well-reported for this purpose where ubiquitous fluids, like glucose or lactate, can be leveraged. However, such biofuel cells need enzymes to complete the catalysis, leading to many prevalent issues like the longevity of enzymes, complicated immobilization, additional mediators etc. Therefore, non-enzymatic glucose biofuel cells (NEGBFCs) are gaining interest due to their cost-effectiveness, high repeatability and excellent stability. However, based on our best knowledge such glucose biofuel cells are not reported in microfluidic environment, and therefore their potential is not exploited. Realization of the functionality of such NEGBFCs in a microscale is crucial to replace them with their enzymatic counterparts. In this work, for the first time, a microfluidic non-enzymatic glucose biofuel cell (μNEGBFC) is developed on a paper-based platform using metallic catalysts. The catalysts for electrocatalytic energy generation is fabricated using electrodeposition method and their detailed physicochemical characterizations are done. The μNEGBFC is capable of producing a power density of 12.5 μW/cm2 with a stable potential of 410 mV. This green power output can be used to operate low-power micro-devices and lab-on-chip sensors in a more continual and viable manner. [Display omitted] • A simple, cost-effective electrodeposition technique was used for electrode fabrication. • Gold deposited anode and copper deposited cathode were used as electrodes. • A paper-based Microfluidic Non-Enzymatic Biofuel Cell (μNGBFC) was constructed. • The developed μNGBFC generated a power density of 12.5 μW/cm2. • The μNGBFC was capable of retaining 56% of the initial power after 72 h. [ABSTRACT FROM AUTHOR]