A highly efficient yet stable salamo-type fluorescent chemosensor with multiple responses to Cu2+ and S2−.

A new salamo-type bisoxime compound H3L has been synthesized and exploited as a highly efficient chemosensor with multiple responses to Cu2+ and S2−. Chemosensor H3L exhibits highly selective and sensitive detection of Cu2+ and S2− simultaneously. The LODs of Cu2+ and S2− were calculated to be 1.5398 × 10−7 and 1.7274 × 10−7 M in DMF-water (9 : 1, v/v) solution, respectively. The color of the chemosensor H3L solution changed from light green to dark green after adding S2− under a 365 nm UV-lamp. The sensing mechanism of the chemosensor H3L was characterized using several methods, including ultraviolet spectroscopy, ESI-mass spectrometry, 1H-NMR and FT-IR spectroscopy. Meanwhile, the crystal structure of the Cu(II) complex, [Cu2(L)]ClO4·2CH3OH, has been determined by X-ray crystallographic analysis. Density Functional Theory (DFT) was employed to further understand the obtained experimental results. [ABSTRACT FROM AUTHOR]