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Discrete Heteropolynuclear Yb/Er Assemblies: Switching on Molecular Upconversion Under Mild Conditions.
- Source :
-
Angewandte Chemie . 10/4/2021, Vol. 133 Issue 41, p22542-22549. 8p. - Publication Year :
- 2021
-
Abstract
- The salts {[Ln2Ln*(Hhmq)3(OAc)3(hfac)2]+ [Ln*(hfac)3(OAc)(MeOH)]−} (Hhmq=2‐methanolquinolin‐8‐oxide, hfac=hexafluoroacetylacetonate; Ln, Ln*=Er, Gd, Yb) feature a discrete heteronuclear cation consisting of two types of lanthanide atoms. The quinolinoxy O‐atom serves as a μ2‐bridge to two Ln atoms and as a μ3‐bridge to all three atoms, with metal⋅⋅⋅metal distances being around 3.7 Å. For 1 ([Yb2Er]+), near‐infrared downshifted luminescence is switched to competitive upconversion luminescence upon irradiation by a 980 nm laser under an extremely low excitation power (0.288 W cm−2) through introduction of fluoride ions. The stability of 1 after addition of fluoride was confirmed by powder X‐ray diffraction and multistage mass spectrometry, associated with the 1H NMR of 6 ([La2Eu]+). More importantly, the at least 20‐fold enhancement of the quantum yield in non‐deuterated solvents at room temperature under low power densities (2 W cm−2) is the highest among the few molecular examples reported. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 133
- Issue :
- 41
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 152654035
- Full Text :
- https://doi.org/10.1002/ange.202107637