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Organic guest molecule induced ultrafast breathing of an epitaxially grown metal–organic framework on a self-assembled monolayer.
- Source :
-
Chemical Communications . 10/11/2021, Vol. 57 Issue 79, p10158-10161. 4p. - Publication Year :
- 2021
-
Abstract
- We report epitaxially grown new two-dimensional metal–organic framework (MOF) thin films on a self-assembled monolayer (SAM). We fabricated these epitaxial thin-films using stepwise layer-by-layer seeding followed by solvothermal treatment. The MOF thin films exhibit ultrafast structural flexibility (through breathing) compared to their bulk samples upon uptake of organic guest molecules. [ABSTRACT FROM AUTHOR]
- Subjects :
- *METAL-organic frameworks
*MONOMOLECULAR films
*THIN films
*MOLECULES
*RESPIRATION
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 57
- Issue :
- 79
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 152887263
- Full Text :
- https://doi.org/10.1039/d1cc03721h