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Giant energy storage density in Ba, La co-doped PbHfO3-based antiferroelectric ceramics by a rolling process.
- Source :
-
Journal of Alloys & Compounds . Dec2021, Vol. 888, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
-
Abstract
- By chemical substitutions with Ba2+ and La3+ at A-site in PbHfO 3 -based ceramics, an ultrahigh energy storage efficiency of 91% and high energy density of 7.3 J cm−3 are achieved simultaneously at 290 kV cm−1 in Pb 0.925 Ba 0.045 La 0.03 (Hf 0.6 Sn 0.4) 0.9925 O 3 ceramics. [Display omitted] Near-zero remanent polarization, high breakdown electric field, high saturation polarization and low electrical hysteresis are necessary conditions for antiferroelectric ceramics to obtain excellent energy storage performance. Here, Pb 0.925 Ba x La 0.075−x (Hf 0.6 Sn 0.4) 0.98125+x/4 O 3 lead-based antiferroelectric ceramics were prepared by a rolling process. The composition modulations of Ba and La are beneficial to adjust the phase switching field, improve the saturation polarization and reduce the electrical hysteresis, leading to an enhanced energy storage performance. Simultaneously, the Pb 0.925 Ba 0.045 La 0.03 (Hf 0.6 Sn 0.4) 0.9925 O 3 ceramic exhibited a high energy storage density of 7.3 J cm−3 and an energy storage efficiency of 91%, revealing that this composition is an outstanding candidate in pulsed energy storage application and lays a foundation for further study on the energy storage performances of PbHfO 3 -based antiferroelectric ceramics. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 888
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 152950427
- Full Text :
- https://doi.org/10.1016/j.jallcom.2021.161539