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Synergistic effects of aryl diazonium modified Few-Layer black Phosphorus/Ultrafine rare earth yttrium oxide with enhancing flame retardancy and catalytic smoke toxicity suppression of epoxy resin.
- Source :
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Applied Surface Science . Jan2022, Vol. 571, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
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Abstract
- [Display omitted] • Few-layer black phosphorus was prepared via a simple hydrothermal Li+ intercalation method. • Aryl diazonium modified black phosphorus/ ultrafine yttrium oxide promisingly reduced the fire hazard of epoxy resins. • The possible mechanism of radical removal and catalytic carbonation was put forward. • This work might have a promising prospect for developing efficient covalent functionalized BP nanocomposites. Black phosphorus (BP), as a promising star of two-dimensional (2D) van der Waals family, has attracted extensive attention for its characteristic dimension effects, mechanical properties and thermal stability. Herein, we report a facile strategy of integrating aryl diazonium modified few Layer black phosphorus with loading of ultrafine yttrium oxide (BP-NH-Y), for reducing the fire hazard of epoxy resin (EP). The results of cone calorimetry test results manifest that the flame retardancy of EP can significantly improve by adding 2 wt% BP-NH-Y, for instance, the peak heat release rate (pHRR) and the total heat release (THR) is reduced by 47.0% and 48.1%, respectively. Especially, adding the BP-NH-Y nanosheets distinctly inhibite the diffusion of EP pyrolysis products (such as toxic CO, hydrocarbons etc.) during flaming. In particular, epoxy composites with only 1.0 wt% BP-NH-Y were able to achieve UL-94 V-0 rating with an oxygen index of more than 30. This work may have a promising prospect for developing efficient covalent functionalized BP nanosheets to meet the needs of sustainable applications. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01694332
- Volume :
- 571
- Database :
- Academic Search Index
- Journal :
- Applied Surface Science
- Publication Type :
- Academic Journal
- Accession number :
- 153007745
- Full Text :
- https://doi.org/10.1016/j.apsusc.2021.151356