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K2Na3[{B6O10(OH)}{B3O4(OH)3}] ⋅ H2O: A Layered Borate Built by Mixed Oxoboron Clusters with Nonlinear‐Optical Property.
- Source :
-
Chemistry - An Asian Journal . 10/18/2021, Vol. 16 Issue 20, p3244-3248. 5p. - Publication Year :
- 2021
-
Abstract
- A new acentric borate, K2Na3[{B6O10(OH)}‐{B3O4(OH)3}] ⋅ H2O (1) has been made under solvothermal condition. 1 has layered structure made by B6O13(OH)‐based chains and B3O5(OH)3‐bridging clusters. Second‐harmonic generation (SHG) measurements reveal that 1 is a phase‐matchable nonlinear optical (NLO) material, showing the SHG signal intensity of 1.8 times that of KDP (KH2PO4). Besides, UV‐Vis diffuse reflectance spectrum shows that 1 has the short deep UV (DUV) absorption cutoff edge of 198 nm. Thermogravimetric analysis reveals it has good thermal stability. Also 1 represents firstly mixed oxoboron clusters‐made 2D layered borate with NLO property. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BORATES
*THERMOGRAVIMETRY
*THERMAL stability
*OXYGEN
*NONLINEAR optics
*REFLECTANCE
Subjects
Details
- Language :
- English
- ISSN :
- 18614728
- Volume :
- 16
- Issue :
- 20
- Database :
- Academic Search Index
- Journal :
- Chemistry - An Asian Journal
- Publication Type :
- Academic Journal
- Accession number :
- 153064585
- Full Text :
- https://doi.org/10.1002/asia.202100869