A novel approach for processing CaAlSiON glass-ceramics by spark plasma sintering: Mechanical and electrical properties.

• Oxynitride glass-ceramics doped with Li-ions were prepared by SPS. • Hardness and reduced elastic modulus decrease with increased Li content. • The conductivity increases with the content of Li for oxynitride samples. • The D.C. conduction mechanism is dominated by Li-ions hopping. • Float glass doped with 6 wt. % has high conductivity than analogue oxynitride glass. Lithium containing glassy materials can be used as solid electrolytes or electrode materials for lithium-ion batteries due to their high energy density. Conventional melt-quenched Ca 11 Al 14 Si 16 O 49 N 10 glass powder containing 24 e/o N, doped with Li-ions (1, 3, and 6 wt. %) and sintered by spark plasma sintering technique (SPS) was studied. The benefits of using SPS to produce glass-ceramics are rapid heating rates compared to conventional consolidation techniques and tuning of properties, adjusting the temperature, holding time (closed to Tg temperature), heating rate (solidification), and pressure (densification) profile during the heat treatment using SPS. Pure glass and glass-ceramic were obtained under identical SPS conditions and compared with pristine oxynitride and soda-lime-silicate (float) glasses. XRD and SEM analysis confirmed that increasing the amount of Li increases the crystallinity in the glass matrix. Nano-indentation analysis showed a decreased hardness and reduced elastic modulus values with the addition of Li-ions. The direct current conductivity increases with the addition of Li due to the high mobility of Li-ions. However, the float glass sample doped with 6 wt.% of Li exhibits even higher values of D.C. conductivity, than the analogously doped Ca 11 Al 14 Si 16 O 49 N 10 glass. The magnitude of activation energy (more than 1 eV) is typical for an ion hopping mechanism and the D.C. conduction mechanism is dominated by Li+ hopping. [ABSTRACT FROM AUTHOR]