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Decarboxylative Hydroxylation of Benzoic Acids.
- Source :
-
Angewandte Chemie International Edition . 11/2/2021, Vol. 60 Issue 45, p24012-24017. 6p. - Publication Year :
- 2021
-
Abstract
- Herein, we report the first decarboxylative hydroxylation to synthesize phenols from benzoic acids at 35 °C via photoinduced ligand‐to‐metal charge transfer (LMCT)‐enabled radical decarboxylative carbometalation. The aromatic decarboxylative hydroxylation is synthetically promising due to its mild conditions, broad substrate scope, and late‐stage applications. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BENZOATES
*HYDROXYLATION
*CHARGE transfer
*BENZOIC acid
*PHENOLS
*PHENOL
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 60
- Issue :
- 45
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 153207706
- Full Text :
- https://doi.org/10.1002/anie.202108971