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Synthesis of ZnO Nanoparticles Loaded on Biochar Derived from Spartina alterniflora with Superior Photocatalytic Degradation Performance.
- Source :
-
Nanomaterials (2079-4991) . Oct2021, Vol. 11 Issue 10, p2479. 1p. - Publication Year :
- 2021
-
Abstract
- Spartina alterniflora is an invasive plant from coastal wetlands, and its use in applications has garnered much interest. In this study, a composite photocatalyst (ZnO@BC) was synthesized by preparing zinc oxide (ZnO) nanoparticles with S. alterniflora extracts, S. alterniflora, and one-step carbonization, which was characterized using scanning electron microscope (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), Raman, X-ray photoelectron spectroscopy, ultraviolet–visible spectroscopy (UV–vis DRS), photoluminescence (PL) and N2 adsorption–desorption isotherm. The degradation capacity and mechanism of malachite green (MG) using ZnO@BC were analyzed under visible irradiation, and the degradation products of malachite green were detected by LC–MS. The results show that ZnO@BC has a larger surface area (83.2 m2/g) and various reactive groups, which enhance its photocatalytic efficiency, with the presence of oxygen vacancy further improving the photocatalytic activity. The total removal rate of malachite green (400 mg/L) using ZnO@BC is up to 98.38%. From the LC–MS analysis, it could be concluded that malachite green is degraded by demethylation, deamination, conjugate structure and benzene ring structure destruction. This study provides a novel idea for the high-value utilization of S. alterniflora. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 20794991
- Volume :
- 11
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Nanomaterials (2079-4991)
- Publication Type :
- Academic Journal
- Accession number :
- 153310446
- Full Text :
- https://doi.org/10.3390/nano11102479