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Selective P-C bond cleavage of tertiary phosphine boranes by sodium.

Authors :
Zhang, Jian-Qiu
Ye, Jing-Jing
Han, Li-Biao
Source :
Phosphorus, Sulfur & Silicon & the Related Elements. 2021, Vol. 196 Issue 11, p961-964. 4p.
Publication Year :
2021

Abstract

Herein reported is the facial modification of tertiary phosphine boranes R3PBH3 by selective cleaving the P-Ph bond by sodium in which the phosphide borohydride R2PNa(BH3) is quantitatively generated and could be easily quenched by electrophiles to furnish a series of new phosphine boranes in high yields. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
*BORANES
*PHOSPHINE
*SODIUM
*SODIUM borohydride
*BOROHYDRIDE
*ELECTROPHILES

Details

Language :
English
ISSN :
10426507
Volume :
196
Issue :
11
Database :
Academic Search Index
Journal :
Phosphorus, Sulfur & Silicon & the Related Elements
Publication Type :
Academic Journal
Accession number :
153311748
Full Text :
https://doi.org/10.1080/10426507.2021.1948851
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