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Electrospun carbon nanofibers functionalized with NiCo2S4 nanoparticles as lightweight, flexible and binder-free cathode for aqueous Ni-Zn batteries.
- Source :
-
Chemical Engineering Journal . Dec2021, Vol. 426, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
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Abstract
- [Display omitted] One-dimensional (1D) electrospun carbon nanofibers functionalized with NiCo 2 S 4 nanoparticles have been synthesized and exhibits excellent performance as a low-cost, lightweight, flexible and binder-free cathode for aqueous Ni-Zn batteries. • Electrospun carbon nanofibers functionalized with NiCo 2 S 4 nanoparticles are synthesized. • The CNF@NiCo 2 S 4 electrode is lightweight, flexible and binder-free. • The CNF@NiCo 2 S 4 exhibits excellent performance for aqueous Ni-Zn batteries. • The quasi-solid-state CNF@NiCo 2 S 4 //Zn battery is also fabricated with polymer electrolyte. Aqueous nickel-zinc (Ni-Zn) batteries hold great promise for large-scale energy storage systems. However, traditional Ni-based cathode electrodes are generally consist of none capacity contribution additives and heavy current collectors, resulting in a low percentage of the active materials. In this regard, developing lightweight, flexible and binder-free cathode electrodes for aqueous Ni-Zn batteries is highly desirable. Herein, for the first time, we develop a simple electrospinning technique to synthesize the one-dimensional (1D) electrospun carbon nanofibers functionalized with ternary NiCo 2 S 4 nanoparticles (denoted as CNF@NiCo 2 S 4) as a lightweight, flexible and binder-free electrode for aqueous Ni-Zn batteries. Based on the self-standing CNF@NiCo 2 S 4 film as cathode, the as-fabricated aqueous CNF@NiCo 2 S 4 //Zn battery exhibits a high capacity of 0.32 mAh cm−2 and 35.9 mAh cm−3 at a current density of 2 mA cm−2, and good rate performance (0.21 mAh cm−2 at 20 mA cm−2) and long-term cycling stability (83% capacity retention at 10 mA cm−2 after 2000 cycles). More importantly, a quasi-solid-state CNF@NiCo 2 S 4 //Zn battery is also fabricated, which also displays an impressive energy density of 362.3 Wh kg−1, indicating the potential towards practical applications. Impressively, the volumetric energy density of CNF@NiCo 2 S 4 //Zn battery are 58.2 mWh cm−3 (liquid) and 45.4 mWh cm−3 (quasi-solid-state), which are much larger than the values of other reported Ni-Zn batteries. Theses results indicate the self-standing CNF@NiCo 2 S 4 film is promising for for next generation electronic applications. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13858947
- Volume :
- 426
- Database :
- Academic Search Index
- Journal :
- Chemical Engineering Journal
- Publication Type :
- Academic Journal
- Accession number :
- 153371174
- Full Text :
- https://doi.org/10.1016/j.cej.2021.130068