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Studying anion-dependent paradoxically fluorescent Cu(II) complexes bearing a pyridine-decorated tetradentate half-salamo-like ligand.
- Source :
-
Inorganica Chimica Acta . Jan2022, Vol. 529, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
-
Abstract
- A new pyridine-decorated half-salamo-like ligand (HL) was designed and synthesized. Three novel anion-dependent Cu(II) complexes [Cu(L)Cl]·CH 3 OH (1), [Cu(L)Br] (2) and [Cu(L)(NO 3)] (3) have been synthesized and characterized structurally. Furthermore, DFT calculations were investigated in the complexes 1 , 2 and 3. Paradoxically, the fluorescence intensities of these Cu(II) complexes are significantly increased compared to the ligand. [Display omitted] • A new pyridine-decorated half-salamo-like ligand was synthesized. • Three anion-dependent Cu(II) complexes 1 , 2 and 3 have been synthesized and characterized structurally. • The fluorescence intensities of these Cu(II) complexes are significantly increased compared to the ligand. A new pyridine-decorated half-salamo-like ligand (HL) was designed and synthesized by a one-pot method. Based on this ligand, the single crystals of three anion-dependent Cu(II) complexes [Cu(L)Cl]·CH 3 OH (1), [Cu(L)Br] (2) and [Cu(L)(NO 3)] (3) have been cultivated successfully and the structural features were determined by single crystal X-ray diffraction analyses. The results showed that the complexes 1 , 2 and 3 have homologous mononuclear structures, in which the five-coordinated Cu(II) atom is not only surrounded by the N 3 O cavity of the ligand (L)- unit, but also coordinated with Cl−, Br− and NO 3 − as auxiliary coordination, respectively. The ligand HL and the complexes 1 , 2 and 3 were characterized via elemental analyses, IR and UV–Vis spectroscopy. The short-range interactions of the complexes 1 , 2 and 3 were investigated by Hirshfeld surfaces analyses. Furthermore, DFT calculations were investigated in the complexes 1 , 2 and 3. Paradoxically, the fluorescence intensities of these Cu(II) complexes are significantly increased compared to the ligand. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00201693
- Volume :
- 529
- Database :
- Academic Search Index
- Journal :
- Inorganica Chimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 153413060
- Full Text :
- https://doi.org/10.1016/j.ica.2021.120634