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Togni‐II Reagent Mediated Selective Hydrotrifluoromethylation and Hydrothiolation of Alkenes†.
- Source :
-
Chinese Journal of Chemistry . Dec2021, Vol. 39 Issue 12, p3429-3434. 6p. - Publication Year :
- 2021
-
Abstract
- Main observation and conclusion: Based on the redox reactions of Togni‐II reagent and thiols, a thiol‐tuned selective functionalization of unactivated olefins was disclosed. In combination with aryl thiols, stoichiometric amount of Togni‐II reagent prompted a hydrotrifluoromethylation of alkenes, in which, aryl thiols played as reductant and hydrogen source; while by utilization of alkyl thiols, catalytic amount of Togni‐II reagent initiated thiol‐ene and thiol‐yne reactions. The reported applications are characterized by their operational simplicity and wide functional group tolerance. [ABSTRACT FROM AUTHOR]
- Subjects :
- *OXIDATION-reduction reaction
*THIOLS
*FUNCTIONAL groups
*ALKENES
Subjects
Details
- Language :
- English
- ISSN :
- 1001604X
- Volume :
- 39
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Chinese Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 153578764
- Full Text :
- https://doi.org/10.1002/cjoc.202100464