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Structural and magnetic property analysis of bulk and nanocrystalline Ni1.8Mn1.2Sn Heusler alloy.
- Source :
-
Journal of Magnetism & Magnetic Materials . Feb2022, Vol. 544, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
-
Abstract
- • Nanocrystallite size effect on structure and magnetic properties of Ni 1.8 Mn 1.2 Sn. • Presence of both full Heusler L2 1 and inverse Heusler XA crystal symmetries. • The sample can be treated as a natural composite of Ni 2 MnSn and Mn 2 NiSn. • Magnetization not following a linear relation with volume fraction of each phase. • Antiferromagnetic coupling between the two phases. • Magnetization value further decreases for ball-milled nanocrystalline sample. • The magnetic ordering in bulk sample follows mean field theory. • For nanocrystalline sample, the magnetic ordering is a short-range type. The effect of nanocrystallite size on crystal structure and magnetic properties of off-stoichiometric Ni 1.8 Mn 1.2 Sn Heusler alloy has been investigated. XRD (X-Ray Diffraction) and HRTEM (High-Resolution Transmission Electron Microscopy) analysis revealed the presence of both the full Heusler (Ni 2 MnSn) L2 1 and inverse Heusler (Mn 2 NiSn) XA crystal symmetries. Hence, the sample can be treated as a natural composite of both phases. However, the magnetic analysis reveals that the magnetization does not follow a linear relationship with the volume fraction of the individual phases. Rather, the antiferromagnetic coupling between the two phases may be responsible for lowering the net magnetization. On the other hand, magnetization value further decreases for ball-milled sample (nanocrystallite size). Critical magnetic behavior analysis reveals that the magnetic ordering in bulk sample follows mean field theory, and for nanocrystalline sample, the magnetic ordering is a short-range type. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03048853
- Volume :
- 544
- Database :
- Academic Search Index
- Journal :
- Journal of Magnetism & Magnetic Materials
- Publication Type :
- Academic Journal
- Accession number :
- 153678742
- Full Text :
- https://doi.org/10.1016/j.jmmm.2021.168656