CuPd alloy decorated SnNb2O6 nanosheets as a multifunctional photocatalyst for semihydrogenation of phenylacetylene under visible light.

[Display omitted] • Cu 3 Pd 1 /SN exhibits a high performance for semihydrogenation of phenylacetylene. • Cu 3 Pd 1 /SN could activate phenylacetylene via C≡C → Nb π-bonded coordination. • The photogenerated electrons facilitate the production of active H. Bimetallic alloy of CuPd nanoclusters decorated SnNb 2 O 6 nanosheet (CuPd/SN) as a multifunctional photocatalyst has been constructed successfully. Compared with SN, CuPd/SN achieves an excellent performance for semihydrogenation of phenylacetylene under visible light irradiation. Especially, CuPd/SN with the Cu:Pd molar ratio of 3:1 exhibits the highest catalytic conversion efficiency for phenylacetylene (99.6%) with high selectivity of phenylethylene (99.4%). In situ FTIR result reveals that SN could activate phenylacetylene via a C≡C → Nb π-bonded coordination which improves the selectivity of phenylethylene. Experiment results indicate that atom Pd in alloy is responsible for dissociation H 2 , while Cu represses the overhydrogenation. Electrochemical measurements suggest that CuPd alloy on SN surface could greatly minimize the recombination of photogenerated electron − hole pairs. The separated electrons further facilitate the production of active H. Hydrogen spillover would transfer active H to Nb site for phenylacetylene semihydrogenation. Finally, a synergetic catalytic mechanism is deeply discussed at molecule scale. This work would provide a deep insight for designing a multifunctional photocatalyst. [ABSTRACT FROM AUTHOR]