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Mechanistic insights into the dry prelithiated WO3 thin films in electrochromic devices.
- Source :
-
Solid State Ionics . Dec2021, Vol. 373, pN.PAG-N.PAG. 1p. - Publication Year :
- 2021
-
Abstract
- While the dry prelithiation method has been extensively applied in WO 3 -based electrochromic devices, the insight of prelithiated WO 3 films is still ambiguous. Herein, the electrochromic and electrochemical performance of the WO 3 films prepared by an in situ dry prelithiation method is investigated. The deposited lithium is calculated to be separated into 47.8% 'active lithium' and 52.2% 'dead lithium'. On one hand, the enhancement of the electrochemical cycling stability and charge density can be ascribed to the preactivation of 'active lithium', which enlarges the surface area for ion transporting. On the other, the irreversible formation of 'dead lithium zone' in the prelithiated WO 3 films originates from 'dead lithium seed', leading to the detriment of optical properties. This work further provides a profound insight into the implication of prelithiated lithium on the electrochemical and electrochromic properties of the WO 3 films. • The prelithiated WO 3 films were prepared by an in situ dry prelithiation method. • Mechanistic insight into the prelithiated WO 3 films in the electrochromic device is clarified. • A complementary electrochromic device with a superior cycling stability over 10,000 cycles is assembled. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ELECTROCHROMIC devices
*THIN film devices
Subjects
Details
- Language :
- English
- ISSN :
- 01672738
- Volume :
- 373
- Database :
- Academic Search Index
- Journal :
- Solid State Ionics
- Publication Type :
- Academic Journal
- Accession number :
- 153847840
- Full Text :
- https://doi.org/10.1016/j.ssi.2021.115814