Origin, accumulation and secondary alteration of natural gas around Qingshui Sub-sag, Liaohe Depression, China: Insights from molecular and isotopic composition.

Fourteen gases and their associated oils were collected at the surface from production wells in the Shahejie Formation, Dongying Formation, and Archean in six zones around the Qingshui Sub-sag of the Liaohe Depression, Bohai Bay Basin. The molecular compositions and carbon and hydrogen isotopic compositions of natural gas were measured. The origin, migration, accumulation, and secondary alteration of natural gas were studied based on the lateral and vertical comparison of natural gas geochemical characteristics. The natural gases include humic-type (δ13C 2 > −29.0‰, δ13C 1 > −43.0‰), sapropelic-type (δ13C 2 < −29.0‰, δ13C 1 > −43.0‰), and secondary microbial (δ13C 1 of −48.5‰, C 1 /(C 2 +C 3) of 46.3, δ13CO 2 of −1.5‰) gases. The humic-type and sapropelic-type gases were derived from the source rocks in the third and fourth members of the Shahejie Formation, respectively. The humic-type gases dominate. The biodegradation level of natural gas in the study area varies, and biodegraded gases are characterized by high Δ13C(C 3 –C 2), low C 3 /C 2 , and low C 3 /iC 4 and are associated with biodegraded oils. The vertical migration of natural gas in the west and east of the Qingshui Sub-sag is limited. There are good additional exploration prospects for humic-type gas, derived from high-maturity source rocks of the third member of the Shahejie Formation in the deep layers (depth >4.5 km) of the Qingshui Sub-sag. Secondary microbial gas is a potential exploration target in the shallow layers (depth <2.5 km). • Humic-type gas is from the source rock of the 3rd member of Shahejie Formation. • Sapropelic-type gas is from the source rock of the 4th member of Shahejie Formation. • Biodegraded gas: 13C-rich propane, depletion of propane and n-butane. • Secondary microbial gas: 13C-rich carbon dioxide and 13C-depleted methane. • Natural gas mainly accumulates near the source rock. [ABSTRACT FROM AUTHOR]