Back to Search
Start Over
Gradually anchoring sulfur into in-situ doped carbon substrate as cathode for Li–S batteries with excellent wide-temperature performance.
- Source :
-
Ceramics International . Jan2022, Vol. 48 Issue 2, p1622-1632. 11p. - Publication Year :
- 2022
-
Abstract
- Carbon spheres, prepared by hydrothermally treating fresh potato starch, is employed as the sulfur host to configure a high-performance cathode substrate candidate for Li–S batteries. As confirmed by experimental results, both the improved the rate and cycle performances of Li–S batteries cathode with gradient sulfur immobilization, are mainly attributed to the confining, adsorption and conduction multi-functions of as-prepared carbon spheres toward polysulfides. Specifically, on starting the discharging/charging cycles, the active material α-S 8 is irreversibly converted to polysulfides and then transformed between β-S 8 and polysulfides during the next charge/discharge cycles. After initialization at 0.1C for 3 cycles, the initial reversible discharge capacities of the Li–S batteries cathode with optimized sulfur amount are 1072.5, 831.3, 780.4, 726.8, 714.3, 702.7 mAh g−1 sulfur at 0.1, 0.5, 1, 2, 3 and 4 C, which is superior to those of the most previously reported reports. Besides that, as-designed potato-derived carbon based composite cathodes exhibits remarkable rate performance and cycling stability even at wide temperature ranging from −40 to 60 °C, which evidently supports the dominant role of as-prepared 3D carbon spheres in boosting the cathode performance for Li–S batteries. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 48
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 153851539
- Full Text :
- https://doi.org/10.1016/j.ceramint.2021.09.241