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Two robust Zn(II)-organic frameworks as dual-functional fluorescent probes for efficient sensing of enrofloxacin and MnO4− anions.
- Source :
-
CrystEngComm . 1/7/2022, Vol. 24 Issue 1, p182-191. 10p. - Publication Year :
- 2022
-
Abstract
- Selective detection of antibiotics and MnO4− is crucial for human health improvement and protecting the environment. Two stable Zn(II)-based metal–organic frameworks (MOFs) {[Zn6(L1)2(NDC)5(μ2-OH)2]·0.5H2O}n (1), and {[Zn(L2)(NDC)]·2H2O}n (2) (H2NDC = 1,4-naphthalenedicarboxylic acid, L1 = 1,5-bis(1-(pyridine-4-ylmethyl)-1H-benzo[d]imidazol-2-yl)pentane, L2 = 1,6-bis(1-(pyridine-4-ylmethyl)-1H-benzo[d]imidazol-2-yl)hexane) were successfully synthesized by adopting the mixed ligands approach. 1 is a rare 3D 3,5,6T23 framework based polynuclear complex group. 2 possesses a 2D sql layer. The two MOFs exhibit excellent chemical and thermal stability. The title compounds are promising dual-functional fluorescent sensors for detecting enrofloxacin/MnO4− anions with high selectivity and sensitivity (Ksv values toward enrofloxacin: 4.29 × 106 L mol−1 for 1 and 4.59 × 106 L mol−1 for 2 and toward MnO4−: 1.05 × 104 for 1, 5.48 × 103 L mol−1 for 2, respectively), which are the first observations of fluorescent MOFs for the sensing of enrofloxacin and MnO4− anions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14668033
- Volume :
- 24
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- CrystEngComm
- Publication Type :
- Academic Journal
- Accession number :
- 154217172
- Full Text :
- https://doi.org/10.1039/d1ce01447a