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Lactonization with concomitant 1,2-aryl migration and alkoxylation mediated by dialkoxyphenyl iodides generated in situ.
- Source :
-
Chemical Communications . 8/4/2021, Vol. 57 Issue 60, p7426-7429. 4p. - Publication Year :
- 2021
-
Abstract
- A series of alkoxylated isobenzofuranones were conveniently synthesized from the reaction of 2-(1-arylvinyl)benzoic acids with PhI(OR)2, generated in situ from the reaction of iodosobenzene (PhIO) with alkyl alcohols. This hypervalent iodine mediated one-pot transformation is postulated to undergo a cascade reaction involving lactonization, 1,2-aryl migration and alkoxylation processes. The organocatalytic and chiral organoiodine-catalyzed asymmetric reactions of the current transformation were also probed. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALKOXYLATION
*ETHANOL
*IODIDES
*BENZOATES
*IODINE
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 57
- Issue :
- 60
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 154432084
- Full Text :
- https://doi.org/10.1039/d1cc03110d