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Facilitating Mg2+ diffusion in high potential LixV2(PO4)3 cathode material with a co-insertion strategy for rechargeable Mg-ion batteries.
- Source :
-
Journal of Power Sources . Feb2022, Vol. 520, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
-
Abstract
- Rechargeable Mg-ion batteries offer high energy density and good safety. However, the lack of cathode materials with high operating potential and considerable capacity is a great challenge for their practical applications. This is limited by the sluggish diffusion of multivalent Mg2+ cations in solid lattices. Here, we propose a co-insertion strategy to facilitate cation diffusions and present a polyanion cathode of Li 3 V 2 (PO 4) 3 to provide high redox potential. The initial charge of the material is associated with the extraction of two Li+ cations, which are co-inserted with Mg2+ from the 0.5 m Mg(ClO 4) 2 /PC electrolyte during the following electrochemical processes. The cation diffusion coefficients are largely enhanced in comparison to the electrode without Li+ co-insertion, and higher capacity is obtained. At room temperature, the Li 3 V 2 (PO 4) 3 electrode delivers 124 mAh g−1 capacity at 100 mA g−1 with discharge plateaus at 0.46 V and −0.44 V vs. Ag/Ag+. A capacity retention of 80% is realized after 300 cycles at 500 mA g−1. A rocking-chair Mg-ion full cell coupling the Li 3 V 2 (PO 4) 3 cathode with an anthraquinone anode achieves 41 mAh g−1 capacity (based on the mass of both electrodes). The work demonstrates a promising pathway for the design of high performance cathode materials for Mg-ion batteries. [Display omitted] • A high potential polyanion cathode of Li 3 V 2 (PO 4) 3 is proposed for Mg-ion batteries. • A co-insertion strategy is revealed to enhance cation diffusion in solid lattices. • The Li 3 V 2 (PO 4) 3 electrode delivers 124 mAh g−1 capacity at 100 mA g−1. • High discharge potentials of 0.46 V and −0.44 V vs. Ag/Ag+ are achieved. • A capacity retention of 80% is realized over 300 cycles with 99.3% CE. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03787753
- Volume :
- 520
- Database :
- Academic Search Index
- Journal :
- Journal of Power Sources
- Publication Type :
- Academic Journal
- Accession number :
- 154658740
- Full Text :
- https://doi.org/10.1016/j.jpowsour.2021.230853