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Auxiliary‐Free Remote Dearomatizative Nitrenoid Transfer for Enantioselective Construction of Spirolactams.
- Source :
-
Advanced Synthesis & Catalysis . 1/18/2022, Vol. 364 Issue 2, p314-318. 5p. - Publication Year :
- 2022
-
Abstract
- An Ir‐catalyzed remote dearomatizative amidation for the enantioselective construction of chiral spirolactams in 70–93% yield with 81–96% ee was developed. This protocol represented a more atom‐economical approach to chiral spirolactams via Ir‐catalyzed nitrenoid transfer without the introduction of a traceless O‐silyl achiral auxiliary. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 364
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 154741826
- Full Text :
- https://doi.org/10.1002/adsc.202101189