Biobased polyporphyrin derived porous carbon electrodes for highly efficient capacitive deionization.

Recently, capacitive deionization (CDI) has attracted considerable interest as a potential desalination technique for seawater. It is thus desirable to develop low-cost, sustainable, and efficient electrode materials for desalination. In this study, the polyporphyrin was prepared by a one-pot reaction from biobased furan derivative, followed by activation to manufacture nitrogen-doped polyporphyrin derived porous carbons (NPPCs) for efficient capacitive deionization. In the presence of KOH as a pore activator, NPPCs exhibited cross-linked interconnected nanosphere chain-like structures inherited from the polyporphyrin backbone with coexisting mesopores and micropores, leading to extremely high specific surface area (2979.3 m2 g−1) and large pore volume (2.22 cm3 g−1). The electrochemical measurements revealed good conductivity, outstanding stability, and extraordinary specific capacitance (328.7 F g−1) of NPPCs, which can be ascribed to rich nitrogen content (8.0 at%) and high Pyrrolic nitrogen ratio. Due to their superior hierarchical porous structure and excellent electrochemical performance, the NPPC-800 electrodes presented a high salt adsorption capacity (SAC) of 35.7 mg g−1 and outstanding cycling stability in 10 mM NaCl solution at 1.2 V during the desalination tests. This work demonstrates the utilization of biobased porous carbon material will pave a prospective way in sustainable and potential applications for CDI technique. [Display omitted] • Nitrogen-doped porous carbons were fabricated from biobased polyporphyrin. • NPPCs exhibited high specific surface areas, large pore volumes and sufficient N content. • NPPCs showed excellent electrochemical specific capacitance up to 328.7 F g−1. • NPPCs electrodes enabled high salt adsorption capacity and stable desalination recyclability. [ABSTRACT FROM AUTHOR]