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2-Imidazolidinone benzofurans as unexpected outcome of the Lewis acid mediated Nenitzescu reaction.
- Source :
-
New Journal of Chemistry . 2/7/2022, Vol. 46 Issue 5, p2028-2032. 5p. - Publication Year :
- 2022
-
Abstract
- The Lewis acid mediated Nenitzescu reaction with piperazinone enaminoesters surprisingly afforded rearranged 2-imidazolidinone 5-hydroxybenzofurans. The reaction was optimised and a scope study was performed. A one-pot two-step procedure was realised starting directly from 1,2-diaminoethane, diethyl acetylene dicarboxylate and 1,4-benzoquinone. A plausible reaction mechanism is proposed. [ABSTRACT FROM AUTHOR]
- Subjects :
- *LEWIS acids
*ETHYLENEDIAMINE
*BENZOFURANS
*ACETYLENE
Subjects
Details
- Language :
- English
- ISSN :
- 11440546
- Volume :
- 46
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- New Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 154970054
- Full Text :
- https://doi.org/10.1039/d1nj04965h