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Acetylene storage performance of [Ni(4,4′-bipyridine)2(NCS)2]n, a switching square lattice coordination network.
- Source :
-
Chemical Communications . 2/4/2022, Vol. 58 Issue 10, p1534-1537. 4p. - Publication Year :
- 2022
-
Abstract
- We report that the previously reported square lattice coordination network [Ni(4,4′-bipyridine)2(NCS)2]n, sql-1-Ni-NCS, undergoes acetylene induced switching between closed (nonporous) and open (porous) phases. The resulting stepped sorption isotherms exhibit temperature controlled steps, consistent high uptake and benchmark working capacity (185 cm−3 g−1 or 189 cm−3, 1–3.2 bar, 288 K) for acetylene storage. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 58
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 155001193
- Full Text :
- https://doi.org/10.1039/d1cc06638b