Green synthesis and use of copper oxide nanoparticles to prepare a highly thermal, antimicrobial, and anticorrosion hybrid coating for mild steel under electron beam irradiation.

Purpose: The purpose of this study is to prepare copper oxide nanoparticles (CuO NPs) in an easy and efficient way using a natural and environmentally friendly substance like ascorbic acid. Various concentrations of these nanoparticles were then added to solvent-free coating formulations to produce highly hydrophobic, corrosion-resistant and antimicrobial hybrid coatings. These hybrid formulations were also used to coat the spent fuel casks for their integrity. Design/methodology/approach: The hybrid coated films were then characterized by X-ray diffraction, Fourier transform infrared spectroscopy (FT-IR), water contact angle and Scanning electron microscope (SEM). In addition, different measurements, namely, mechanical, physical, chemical, thermal, corrosion tests, open circuit potential and antimicrobial activity of these hybrid films were performed. Findings: The results showed that the copper oxide was prepared at nanometer scales with good homogeneity and diffusion in the epoxy acrylate matrix. It also showed that some hybrid coatings have high corrosion resistance, strong hardness, excellent water resistance, remarkable antimicrobial activity and high thermal stability compared to virgin epoxy acrylates. Originality/value: The formula containing 0.5% CuO NPs was found to provide the highest corrosion protection and antimicrobial activity for mild steel in 3.5% sodium chloride (NaCl). [ABSTRACT FROM AUTHOR]