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The use of photoionization cross section for evaluating contribution of continuum to the blackbody radiation induced shift and broadening of Rydberg-state energy levels of group IIb ions.
- Source :
-
Journal of Quantitative Spectroscopy & Radiative Transfer . Apr2022, Vol. 280, pN.PAG-N.PAG. 1p. - Publication Year :
- 2022
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Abstract
- • The quantitative data for contribution of continuum to Rydberg-state energy-level shift and broadening is determined for group IIb ions • Asymptotic equations for the rates of the blackbody radiation (BBR) induced ionization and energy-level shifts are presented analytically in terms of Rydberg-states binding energy and photoionization cross section • Quantitative analysis is given for angular-momentum dependence of photoionization cross section of Rydberg-state atoms and ions • Analytic equations for amplitudes of bound-bound transitions from Rydberg states in the quantum defect approach are written in terms of generalized hypergeometric polynomials. General properties of n -dependence at the threshold and regularities of above-threshold ionization cross sections for states with high principal quantum numbers n and arbitrary angular momenta l are determined and used for evaluating the blackbody-radiation(BBR)-induced ionization broadening of n S, n P, n D and n F Rydberg-state energy levels of the group IIb ions Zn + , Cd + , Hg + at temperatures from T = 100 K to T = 3000 K. The contributions to the energy level shifts from transitions into continuum are also determined with the use of the ionization cross sections. The single-electron quantum defect method (QDM) was used, which appears rather precise and suitable for calculating the amplitudes of radiation transitions from Rydberg states, and specifically for summation of matrix-element-dependent terms over infinite number of discrete states. The dependencies on temperature and binding energy are determined and approximate analytic equations are proposed for simplified evaluations of the BBR-induced ionization broadening and shifts. Numerical parameters of approximate equations are tabulated for S, P, D and F Rydberg states of the group IIb ions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00224073
- Volume :
- 280
- Database :
- Academic Search Index
- Journal :
- Journal of Quantitative Spectroscopy & Radiative Transfer
- Publication Type :
- Academic Journal
- Accession number :
- 155428269
- Full Text :
- https://doi.org/10.1016/j.jqsrt.2022.108068