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Quaternary Phosphonium Carboxylates: Structure, Dynamics and Intriguing Olefination Mechanism.
- Source :
-
Synthesis . 2022, Vol. 54 Issue 7, p1745-1752. 8p. - Publication Year :
- 2022
-
Abstract
- We have earlier shown how the Wittig chemistry can be done using novel Eigenbase phosphonium carboxylate reagents. Here we discuss the phenomenon of ion pairing, their solution tautomerism, solid-state structure, and mechanistic aspects of olefination. The results point to a complex process involving unfamiliar H-bond-driven ion-pair equilibria followed by standard Wittig reaction steps. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00397881
- Volume :
- 54
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Synthesis
- Publication Type :
- Academic Journal
- Accession number :
- 155811267
- Full Text :
- https://doi.org/10.1055/s-0037-1610788