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Band Engineering Induced Conducting 2H‐Phase MoS2 by PdSRe Sites Modification for Hydrogen Evolution Reaction.
- Source :
-
Advanced Energy Materials . 3/24/2022, Vol. 12 Issue 12, p1-10. 10p. - Publication Year :
- 2022
-
Abstract
- The electronic band structure of MoS2 exerts far‐ranging effects on the applications of these materials, ranging from chemical catalysis, electronic, and magnetic behaviors. However, the underlying relationship between the electronic band structure and activity is largely unknown in heterogeneous catalysis including the hydrogen evolution reaction, partly due to the lack of a controllable methodology to achieve desirable electronic band structures in the 2H‐phase MoS2. Herein it is demonstrated that dual dopants can engineer the band structure of MoS2 by substituting into the adjacent Mo sites. Specifically, these constructed PdRe dimers bridged by sulfur (PdSRe sites) introduce conducting electronic states around the Fermi level to increase the metallic characteristics of MoS2, resulting in metallic‐like behavior, which is initially semiconducting. Furthermore, the efficacy of inducing a phase conversion from 2H to metallic 1T is higher for codoping with dual dopants as compared to that for the use of a single dopant, thereby generating more intrinsically active PdS*Mo sites to further increase active sites density. Ultimately, this leads to the MoS2 catalyst showing a low overpotential of 46 mV at a current density of 10 mA cm−2 and a high exchange current density of 1.524 mA cm−2, along with superior operating durability. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16146832
- Volume :
- 12
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Advanced Energy Materials
- Publication Type :
- Academic Journal
- Accession number :
- 155938697
- Full Text :
- https://doi.org/10.1002/aenm.202103823