Heterostructured ZIF-8/lamellar talc composites incorporated polydimethylsiloxane membrane with enhanced separation performance for butanol recovery.

In this study, heterostructured MOF/lamellar talc composites was successfully synthesized by in-situ growth of zeolitic imidazolate framework-8 (ZIF-8) nanoparticles on acidified black talc (ABT) and introduced into polydimethylsiloxane (PDMS) matrix to prepare high-performance mixed matrix membranes (MMMs) via spin coating and thermal cross-linking. The submicron-size natural lamellar black talc (BT) was first explored as stable carrier to synthesize laminated composite with continuous MOF phase. Owing to its silica-oxygen tetrahedral structure, the resultant laminated composite presented good compatibility with PDMS matrix, avoiding the formation of interfacial defect between polymer and nanoparticles. Moreover, well-dispersed and continuous ZIF-8 nanoparticles on lamellar nanosheets had preferential adsorption effect for alcohol, enhancing the selectivity of membranes. The coupling effects of graphene-like lamellar structure from talc and sequential transport channels from ZIF-8 attributed to greatly enhance permeation flux. Various techniques such as FESEM, TEM, FTIR, XRD and EDS were applied to investigate the morphology and structure of composites and membranes, and pervaporation experiments were applied to probe the behavior of polymer-based composite membranes. High performance defect-free ZIF-8@ABT/PDMS MMMs exhibited excellent total permeate flux of 1711 g m−2 h−1 with very competitive separation factor of 41 for low concentration n-butanol recovery. [Display omitted] • Heterostructured composite was first achieved by in-situ growth of MOF on talc nanosheet. • MMMs were obtained by introducing lamellar composites into PDMS matrix via spin-coating. • Interfacial defect was avoided by good compatibility between ZIF-8@ABT and PDMS matrix. • Preferential adsorption and unobstructed pathway were achieved by MOFs and lamellar ABT. • Stable ZIF-8@ABT/PDMS membranes exhibited excellent performance for butanol recovery. [ABSTRACT FROM AUTHOR]